Spidey Jumps the Thumper - S1.E9

The Thumper (Hattie Winston) was a spoiled little rich girl who did not get a yellow pony for her birthday. Turning to a life of crime after the cake and ice cream, the Thumper fancies herself as Napoleon Bonaparte. She assaults two citizens (Luis Avalos and Skip Hinnant) with an oversized boxing glove hidden inside her coat a la Napoleon's famous pose. Spidey catches her, but he too is thumped. He regains his senses and traps her in his web. The opening screenshot shows the Thumper landing a blow on Spidey.